{"id":4287,"date":"2023-08-29T08:05:37","date_gmt":"2023-08-29T08:05:37","guid":{"rendered":"https:\/\/plassmat.cnrs-imn.fr\/techniques-and-equipment\/solid-state-nuclear-magnetic-resonance\/"},"modified":"2024-01-30T15:20:45","modified_gmt":"2024-01-30T15:20:45","slug":"solid-state-nuclear-magnetic-resonance","status":"publish","type":"page","link":"https:\/\/plassmat.cnrs-imn.fr\/en\/techniques-and-equipment\/solid-state-nuclear-magnetic-resonance\/","title":{"rendered":"Solid-state nuclear magnetic resonance"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-page\" data-elementor-id=\"4287\" class=\"elementor elementor-4287 elementor-193\" data-elementor-post-type=\"page\">\n\t\t\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-e7be2cd elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"e7be2cd\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-top-column elementor-element elementor-element-70dff61\" data-id=\"70dff61\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-d7deb96 elementor-widget elementor-widget-breadcrumbs\" data-id=\"d7deb96\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"breadcrumbs.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t<p id=\"breadcrumbs\"><span><span><a href=\"https:\/\/plassmat.cnrs-imn.fr\/en\/home\/\">Home<\/a><\/span><\/span><\/p>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-1267f4e elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"1267f4e\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-a14af36\" data-id=\"a14af36\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-d2afb61 elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"d2afb61\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-inner-column elementor-element elementor-element-ea849c8\" data-id=\"ea849c8\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-f5d24c2 elementor-widget elementor-widget-heading\" data-id=\"f5d24c2\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"heading.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t<h1 class=\"elementor-heading-title elementor-size-default\">Solid-state nuclear magnetic resonance<\/h1>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-e7a63e7 elementor-widget elementor-widget-text-editor\" data-id=\"e7a63e7\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>Solid-state Nuclear Magnetic Resonance (NMR) provides <strong>information about the local chemical environment<\/strong> of an atom.<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-1710cff elementor-widget elementor-widget-text-editor\" data-id=\"1710cff\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>It is a well-suited tool for a better understanding of the structure of materials, whether crystallized or amorphous, in order to establish a link with their physico-chemical properties.<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-f884d72 elementor-widget elementor-widget-text-editor\" data-id=\"f884d72\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>Where most characterization techniques focus on electrons, NMR focuses on nuclei. It consists in <strong>detecting variations in the magnetization of atomic nuclei<\/strong> when acted upon by a powerful magnetic field and an exciting electromagnetic wave.<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-1289798 elementor-section-boxed elementor-section-height-default elementor-section-height-default elementor-invisible\" data-id=\"1289798\" data-element_type=\"section\" data-e-type=\"section\" data-settings=\"{&quot;animation&quot;:&quot;slideInUp&quot;}\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-inner-column elementor-element elementor-element-310327a\" data-id=\"310327a\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-1e791c7 elementor-widget__width-auto elementor-widget-mobile__width-inherit elementor-widget elementor-widget-image\" data-id=\"1e791c7\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<img fetchpriority=\"high\" decoding=\"async\" width=\"512\" height=\"512\" src=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon.png\" class=\"attachment-full size-full wp-image-3533\" alt=\"\" srcset=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon.png 512w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-300x300.png 300w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-150x150.png 150w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-270x270.png 270w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-192x192.png 192w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-180x180.png 180w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-32x32.png 32w\" sizes=\"(max-width: 512px) 100vw, 512px\" \/>\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-f5e6f8c elementor-widget__width-auto elementor-widget-mobile__width-inherit elementor-widget elementor-widget-heading\" data-id=\"f5e6f8c\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"heading.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t<h3 class=\"elementor-heading-title elementor-size-default\">Our solid-state NMR instruments<\/h3>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-a65e7ef elementor-section-boxed elementor-section-height-default elementor-section-height-default elementor-invisible\" data-id=\"a65e7ef\" data-element_type=\"section\" data-e-type=\"section\" data-settings=\"{&quot;animation&quot;:&quot;slideInUp&quot;}\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-33 elementor-inner-column elementor-element elementor-element-b302263 plateau-equip\" data-id=\"b302263\" data-element_type=\"column\" data-e-type=\"column\" data-settings=\"{&quot;background_background&quot;:&quot;classic&quot;}\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t<div class=\"elementor-background-overlay\"><\/div>\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-edeb90b elementor-widget elementor-widget-text-editor\" data-id=\"edeb90b\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>Bruker Avance III 500 MHz spectrometer<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-3858b8c elementor-view-stacked elementor-shape-circle elementor-widget elementor-widget-icon\" data-id=\"3858b8c\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"icon.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-icon-wrapper\">\n\t\t\t<a class=\"elementor-icon\" href=\"https:\/\/plassmat.cnrs-imn.fr\/en\/techniques-and-equipment\/solid-state-nuclear-magnetic-resonance\/bruker-avance-iii-500-mhz-spectrometer\/\">\n\t\t\t<i aria-hidden=\"true\" class=\"fas fa-angle-right\"><\/i>\t\t\t<\/a>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-33 elementor-inner-column elementor-element elementor-element-c32072c plateau-equip\" data-id=\"c32072c\" data-element_type=\"column\" data-e-type=\"column\" data-settings=\"{&quot;background_background&quot;:&quot;classic&quot;}\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t<div class=\"elementor-background-overlay\"><\/div>\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-d7289b3 elementor-widget elementor-widget-text-editor\" data-id=\"d7289b3\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>Bruker NEO 300 MHz spectrometer<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-b62874b elementor-view-stacked elementor-shape-circle elementor-widget elementor-widget-icon\" data-id=\"b62874b\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"icon.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-icon-wrapper\">\n\t\t\t<a class=\"elementor-icon\" href=\"https:\/\/plassmat.cnrs-imn.fr\/en\/techniques-and-equipment\/solid-state-nuclear-magnetic-resonance\/bruker-neo-300-mhz-spectrometer\/\">\n\t\t\t<i aria-hidden=\"true\" class=\"fas fa-angle-right\"><\/i>\t\t\t<\/a>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-33 elementor-inner-column elementor-element elementor-element-9156761 plateau-equip\" data-id=\"9156761\" data-element_type=\"column\" data-e-type=\"column\" data-settings=\"{&quot;background_background&quot;:&quot;classic&quot;}\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t<div class=\"elementor-background-overlay\"><\/div>\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-9d12085 elementor-widget elementor-widget-text-editor\" data-id=\"9d12085\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>Bruker Avance III 200 MHz spectrometer<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-328ae26 elementor-view-stacked elementor-shape-circle elementor-widget elementor-widget-icon\" data-id=\"328ae26\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"icon.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-icon-wrapper\">\n\t\t\t<a class=\"elementor-icon\" href=\"https:\/\/plassmat.cnrs-imn.fr\/en\/techniques-and-equipment\/solid-state-nuclear-magnetic-resonance\/bruker-avance-iii-200-mhz-spectrometer\/\">\n\t\t\t<i aria-hidden=\"true\" class=\"fas fa-angle-right\"><\/i>\t\t\t<\/a>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-edd51e0 elementor-invisible\" data-id=\"edd51e0\" data-element_type=\"column\" data-e-type=\"column\" data-settings=\"{&quot;background_background&quot;:&quot;gradient&quot;,&quot;animation&quot;:&quot;slideInRight&quot;}\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-323ce1a elementor-icon-list--layout-traditional elementor-list-item-link-full_width elementor-widget elementor-widget-icon-list\" data-id=\"323ce1a\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"icon-list.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<ul class=\"elementor-icon-list-items\">\n\t\t\t\t\t\t\t<li class=\"elementor-icon-list-item\">\n\t\t\t\t\t\t\t\t\t\t\t<span class=\"elementor-icon-list-icon\">\n\t\t\t\t\t\t\t<i aria-hidden=\"true\" class=\"fas fa-envelope\"><\/i>\t\t\t\t\t\t<\/span>\n\t\t\t\t\t\t\t\t\t\t<span class=\"elementor-icon-list-text\">Contact and rates<\/span>\n\t\t\t\t\t\t\t\t\t<\/li>\n\t\t\t\t\t\t<\/ul>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-88e9c2a elementor-widget elementor-widget-text-editor\" data-id=\"88e9c2a\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>To know the rates and have access to our solid-state NMR instruments, please contact us by email:<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-e5705ab elementor-align-left elementor-mobile-align-justify elementor-widget elementor-widget-button\" data-id=\"e5705ab\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"button.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<div class=\"elementor-button-wrapper\">\n\t\t\t\t\t<a class=\"elementor-button elementor-button-link elementor-size-sm\" href=\"mailto:rmn-plassmat@cnrs-imn.fr\">\n\t\t\t\t\t\t<span class=\"elementor-button-content-wrapper\">\n\t\t\t\t\t\t\t\t\t<span class=\"elementor-button-text\">rmn-plassmat@cnrs-imn.fr<\/span>\n\t\t\t\t\t<\/span>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-7c99a54 elementor-icon-list--layout-traditional elementor-list-item-link-full_width elementor-widget elementor-widget-icon-list\" data-id=\"7c99a54\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"icon-list.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<ul class=\"elementor-icon-list-items\">\n\t\t\t\t\t\t\t<li class=\"elementor-icon-list-item\">\n\t\t\t\t\t\t\t\t\t\t<span class=\"elementor-icon-list-text\">Research networks &amp; partnerships<\/span>\n\t\t\t\t\t\t\t\t\t<\/li>\n\t\t\t\t\t\t<\/ul>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-4a2c96b elementor-widget elementor-widget-text-editor\" data-id=\"4a2c96b\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<ul><li>Member of the F\u00e9d\u00e9ration RMN Solide Hauts Champs (FR2950 CNRS)<\/li><li><p>National (CEA, Montpellier and Amiens universities) and international (Australia, Canada, Italy, UK and South Korea) academic collaborations.<\/p><\/li><li>Collaboration with Umicore to characterize surface impurities on electrode materials for lithium batteries (<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acsami.2c09358?ref=PDF\" target=\"_blank\" rel=\"noopener\">read the publication<\/a>).<\/li><\/ul>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-e411073 elementor-section-boxed elementor-section-height-default elementor-section-height-default elementor-invisible\" data-id=\"e411073\" data-element_type=\"section\" data-e-type=\"section\" data-settings=\"{&quot;animation&quot;:&quot;slideInUp&quot;}\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-top-column elementor-element elementor-element-2efbd99 elementor-hidden-mobile\" data-id=\"2efbd99\" data-element_type=\"column\" data-e-type=\"column\" data-settings=\"{&quot;background_background&quot;:&quot;gradient&quot;}\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-cdd4efa elementor-widget elementor-widget-spacer\" data-id=\"cdd4efa\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"spacer.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-spacer\">\n\t\t\t<div class=\"elementor-spacer-inner\"><\/div>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-top-column elementor-element elementor-element-54159ac\" data-id=\"54159ac\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-e3df5ad elementor-reverse-mobile elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"e3df5ad\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-inner-column elementor-element elementor-element-27b9932\" data-id=\"27b9932\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-e2b3fee elementor-widget__width-auto elementor-widget-mobile__width-inherit elementor-widget elementor-widget-image\" data-id=\"e2b3fee\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<img fetchpriority=\"high\" decoding=\"async\" width=\"512\" height=\"512\" src=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon.png\" class=\"attachment-full size-full wp-image-3533\" alt=\"\" srcset=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon.png 512w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-300x300.png 300w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-150x150.png 150w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-270x270.png 270w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-192x192.png 192w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-180x180.png 180w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/cropped-favicon-32x32.png 32w\" sizes=\"(max-width: 512px) 100vw, 512px\" \/>\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-dea557c elementor-widget__width-auto elementor-widget-mobile__width-inherit elementor-widget elementor-widget-heading\" data-id=\"dea557c\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"heading.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t<h3 class=\"elementor-heading-title elementor-size-default\">Examples and applications<\/h3>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-8eb0179 elementor-widget elementor-widget-text-editor\" data-id=\"8eb0179\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>The solid-state NMR equipment of the PLASSMAT platform has contributed to the characterization of numerous types of materials. Examples include materials for <strong>photovoltaic<\/strong> (<sup>119<\/sup>Sn, <sup>65<\/sup>Cu, <sup>7<\/sup>Li, <sup>67<\/sup>Zn, <sup>77<\/sup>Se, <sup>113<\/sup>Cd) and <strong>polymers<\/strong> (<sup>13<\/sup>C) and <strong>hybrid perovskites<\/strong> (<sup>207<\/sup>Pb,<sup>119<\/sup>Sn, <sup>13<\/sup>C, <sup>15<\/sup>N) and <strong>battery materials<\/strong> (<sup>7<\/sup>Li, <sup>6<\/sup>Li, <sup>19<\/sup>F, <sup>31<\/sup>P, <sup>13<\/sup>C, <sup>29<\/sup>Si), the <strong> clays<\/strong> (<sup>29<\/sup>Si, <sup>27<\/sup>Al, <sup>23<\/sup>Na), hydraulic binders or <strong>geopolymers<\/strong> (<sup>29<\/sup>Si, <sup>27<\/sup>Al, <sup>23<\/sup>Na) or <strong>glass<\/strong> or glass-ceramics (<sup>11<\/sup>B, <sup>23<\/sup>Na, <sup>17<\/sup>O, <sup>29<\/sup>Si, <sup>27<\/sup>Al,<sup>19<\/sup>F).<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<div class=\"elementor-element elementor-element-2afff59 elementor-widget-divider--view-line elementor-widget elementor-widget-divider\" data-id=\"2afff59\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"divider.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-divider\">\n\t\t\t<span class=\"elementor-divider-separator\">\n\t\t\t\t\t\t<\/span>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-255c559 elementor-reverse-mobile elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"255c559\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-ec3c30b\" data-id=\"ec3c30b\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-95c528b elementor-widget elementor-widget-text-editor\" data-id=\"95c528b\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>NMR allows to <strong>characterize poorly-crystalline or amorphous materials<\/strong>:<\/p>\n<ul>\n<li>Left: <sup>29<\/sup>Si MAS NMR monitoring of the appearance of C-A-S-H cementitious phases over time during lime treatment of a calcium bentonite (<a href=\"https:\/\/hal.science\/hal-00864696v1\" target=\"_blank\" rel=\"noopener\">read the publication<\/a>);<\/li>\n<li>Middle: determination of the B<sup>III<\/sup>\/B<sup>IV<\/sup> ratio by MAS NMR of <sup>11<\/sup>Bin borosilicate nuclear glass (<a href=\"https:\/\/hal.science\/hal-02613200v1\" target=\"_blank\" rel=\"noopener\">read the publication<\/a>);<\/li>\n<li>Right: MAS NMR monitoring of <sup>27<\/sup>Al during dehydroxylation of a clay at different calcination temperatures (<a href=\"https:\/\/hal.science\/hal-03109843v1\" target=\"_blank\" rel=\"noopener\">see publication<\/a>).<\/li>\n<\/ul>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-7e841e0\" data-id=\"7e841e0\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-7b31112 elementor-widget elementor-widget-image\" data-id=\"7b31112\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple1.jpg\" data-elementor-open-lightbox=\"yes\" data-elementor-lightbox-title=\"RMN-exemple1\" data-e-action-hash=\"#elementor-action%3Aaction%3Dlightbox%26settings%3DeyJpZCI6MzU0MCwidXJsIjoiaHR0cHM6XC9cL3BsYXNzbWF0LmNucnMtaW1uLmZyXC93cC1jb250ZW50XC91cGxvYWRzXC8yMDIzXC8wOFwvUk1OLWV4ZW1wbGUxLmpwZyJ9\">\n\t\t\t\t\t\t\t<img decoding=\"async\" width=\"934\" height=\"518\" src=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple1.jpg\" class=\"attachment-full size-full wp-image-3540\" alt=\"\" srcset=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple1.jpg 934w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple1-300x166.jpg 300w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple1-768x426.jpg 768w\" sizes=\"(max-width: 934px) 100vw, 934px\" \/>\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<div class=\"elementor-element elementor-element-be331e9 elementor-widget-divider--view-line elementor-widget elementor-widget-divider\" data-id=\"be331e9\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"divider.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-divider\">\n\t\t\t<span class=\"elementor-divider-separator\">\n\t\t\t\t\t\t<\/span>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-947daaa elementor-reverse-mobile elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"947daaa\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-edbf4a2\" data-id=\"edbf4a2\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-7d993c0 elementor-widget elementor-widget-text-editor\" data-id=\"7d993c0\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>Using spectrometers with different fields is sometimes essential to <strong>unambiguously determine the interaction parameters<\/strong> of the sample. For example, nuclei such as those of copper or vanadium, may exhibit chemical shift anisotropy and a quadrupolar interaction of similar magnitude. Obtaining multi-field spectra is of great help in separating these interactions, which depend on the field in opposite ways.<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-aa6c710 elementor-widget elementor-widget-text-editor\" data-id=\"aa6c710\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>On the right, you can see <sup>65<\/sup>CuNMR spectra of the Cu<sub>2<\/sub>SnS<sub>3<\/sub> compound acquired under MAS or static (WURST excitation) conditions at 2 different magnetic fields. These different experimental conditions enabled us to unambiguously determine the 8 interaction parameters associated with each of the 2 crystallographic sites (N and W).<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-f9b216c elementor-align-left elementor-mobile-align-justify elementor-widget elementor-widget-button\" data-id=\"f9b216c\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"button.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<div class=\"elementor-button-wrapper\">\n\t\t\t\t\t<a class=\"elementor-button elementor-button-link elementor-size-sm\" href=\"http:\/\/dx.doi.org\/10.1021\/acs.chemmater.8b01182\" target=\"_blank\">\n\t\t\t\t\t\t<span class=\"elementor-button-content-wrapper\">\n\t\t\t\t\t\t\t\t\t<span class=\"elementor-button-text\">Read the publication<\/span>\n\t\t\t\t\t<\/span>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-6e1961f\" data-id=\"6e1961f\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-8b4bb60 elementor-widget elementor-widget-image\" data-id=\"8b4bb60\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/shif_comp-1.png\" data-elementor-open-lightbox=\"yes\" data-elementor-lightbox-title=\"shif_comp\" data-e-action-hash=\"#elementor-action%3Aaction%3Dlightbox%26settings%3DeyJpZCI6MzYwMywidXJsIjoiaHR0cHM6XC9cL3BsYXNzbWF0LmNucnMtaW1uLmZyXC93cC1jb250ZW50XC91cGxvYWRzXC8yMDIzXC8xMFwvc2hpZl9jb21wLTEucG5nIn0%3D\">\n\t\t\t\t\t\t\t<img decoding=\"async\" width=\"1565\" height=\"252\" src=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/shif_comp-1.png\" class=\"attachment-full size-full wp-image-3603\" alt=\"\" srcset=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/shif_comp-1.png 1565w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/shif_comp-1-300x48.png 300w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/shif_comp-1-1024x165.png 1024w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/shif_comp-1-768x124.png 768w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/shif_comp-1-1536x247.png 1536w\" sizes=\"(max-width: 1565px) 100vw, 1565px\" \/>\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<div class=\"elementor-element elementor-element-f8bacab elementor-widget-divider--view-line elementor-widget elementor-widget-divider\" data-id=\"f8bacab\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"divider.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-divider\">\n\t\t\t<span class=\"elementor-divider-separator\">\n\t\t\t\t\t\t<\/span>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-e1a00bb elementor-reverse-mobile elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"e1a00bb\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-56e8495\" data-id=\"56e8495\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-9032124 elementor-widget elementor-widget-text-editor\" data-id=\"9032124\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>The selective nature of NMR (the response of each type of nucleus is acquired independently) can allow <strong>isolating the signature of nuclei present in small quantities<\/strong> in a material without being hindered by signals from other chemical elements.<\/p>\n<p>NMR spectra (MAS and 3QMAS) of <sup>27<\/sup>Al in the crystalline compounds (In<sub>1-x<\/sub>Al<sub>x<\/sub>)S<sub>3<\/sub> were used to determine the different sites occupied by the aluminum atoms and quantify the occupancy rates depending on x.<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-f51b346 elementor-align-left elementor-mobile-align-justify elementor-widget elementor-widget-button\" data-id=\"f51b346\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"button.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<div class=\"elementor-button-wrapper\">\n\t\t\t\t\t<a class=\"elementor-button elementor-button-link elementor-size-sm\" href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/cm201830e\" target=\"_blank\">\n\t\t\t\t\t\t<span class=\"elementor-button-content-wrapper\">\n\t\t\t\t\t\t\t\t\t<span class=\"elementor-button-text\">Read the publication<\/span>\n\t\t\t\t\t<\/span>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-e5eb950\" data-id=\"e5eb950\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-8431751 elementor-widget elementor-widget-image\" data-id=\"8431751\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/ex3_compress.jpg\" data-elementor-open-lightbox=\"yes\" data-elementor-lightbox-title=\"ex3_compress\" data-e-action-hash=\"#elementor-action%3Aaction%3Dlightbox%26settings%3DeyJpZCI6MzU3OCwidXJsIjoiaHR0cHM6XC9cL3BsYXNzbWF0LmNucnMtaW1uLmZyXC93cC1jb250ZW50XC91cGxvYWRzXC8yMDIzXC8xMFwvZXgzX2NvbXByZXNzLmpwZyJ9\">\n\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"996\" height=\"319\" src=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/ex3_compress.jpg\" class=\"attachment-full size-full wp-image-3578\" alt=\"\" srcset=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/ex3_compress.jpg 996w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/ex3_compress-300x96.jpg 300w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/ex3_compress-768x246.jpg 768w\" sizes=\"(max-width: 996px) 100vw, 996px\" \/>\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<div class=\"elementor-element elementor-element-6900954 elementor-widget-divider--view-line elementor-widget elementor-widget-divider\" data-id=\"6900954\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"divider.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-divider\">\n\t\t\t<span class=\"elementor-divider-separator\">\n\t\t\t\t\t\t<\/span>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-8f97054 elementor-reverse-mobile elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"8f97054\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-953bf3d\" data-id=\"953bf3d\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-b1a529a elementor-widget elementor-widget-text-editor\" data-id=\"b1a529a\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>NMR also provides <strong>information on the connectivity or spatial relationships between atoms<\/strong> in a material.<\/p>\n<\/p>\n<p>On the left, an INDEQUATE NMR spectrum of <sup>119<\/sup>Sn showing the connectivities (through chemical bonds) between the different <sup>119<\/sup>Sn sites in a stannate.<\/p>\n<\/p>\n<p>On the right, <sup>23<\/sup>Na-<sup>31<\/sup>PD-HMQC correlation spectrum showing the spatial proximities between the different <sup>31<\/sup>P and <sup>23<\/sup>Na sites of the Ca<sub>9.5<\/sub>Mg<sub>0.5<\/sub>Na(PO<sub>4<\/sub>)<sub>7<\/sub> compound.<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-9637b58\" data-id=\"9637b58\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-06e89f5 elementor-widget elementor-widget-image\" data-id=\"06e89f5\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/Fig7.jpg\" data-elementor-open-lightbox=\"yes\" data-elementor-lightbox-title=\"Fig7\" data-e-action-hash=\"#elementor-action%3Aaction%3Dlightbox%26settings%3DeyJpZCI6MzYwMSwidXJsIjoiaHR0cHM6XC9cL3BsYXNzbWF0LmNucnMtaW1uLmZyXC93cC1jb250ZW50XC91cGxvYWRzXC8yMDIzXC8xMFwvRmlnNy5qcGcifQ%3D%3D\">\n\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"956\" height=\"349\" src=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/Fig7.jpg\" class=\"attachment-full size-full wp-image-3601\" alt=\"\" srcset=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/Fig7.jpg 956w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/Fig7-300x110.jpg 300w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/Fig7-768x280.jpg 768w\" sizes=\"(max-width: 956px) 100vw, 956px\" \/>\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<div class=\"elementor-element elementor-element-2199c0b elementor-widget-divider--view-line elementor-widget elementor-widget-divider\" data-id=\"2199c0b\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"divider.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-divider\">\n\t\t\t<span class=\"elementor-divider-separator\">\n\t\t\t\t\t\t<\/span>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-89df7b3 elementor-widget elementor-widget-text-editor\" data-id=\"89df7b3\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>NMR can be used to <strong>characterize materials for batteries<\/strong>, as can be seen from these 3 examples:<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-d1321c7 elementor-reverse-mobile elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"d1321c7\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-761e1f2\" data-id=\"761e1f2\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-5c68d08 elementor-widget elementor-widget-text-editor\" data-id=\"5c68d08\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>Right, <sup>7<\/sup>Li MAS NMR spectra of lithiated species on the surface of LiNi<sub>0.5<\/sub>Mn<sub>0.5<\/sub>O<sub>2<\/sub> electrode material. Chemical shifts (~0 ppm) correspond with diamagnetic species whose broad rotational band envelopes demonstrate strong interaction with the underlying paramagnetic material. As the thickness of the surface deposit increases, the width of the signal decreases, indicating a decrease in the dipolar interaction between the paramagnetic centers of (LiNi<sub>0.5<\/sub>Mn<sub>0.5<\/sub>O<sub>2<\/sub>) and the <sup>7<\/sup>Li nuclei of the diamagnetic species.<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-c51002f elementor-align-left elementor-mobile-align-justify elementor-widget elementor-widget-button\" data-id=\"c51002f\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"button.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<div class=\"elementor-button-wrapper\">\n\t\t\t\t\t<a class=\"elementor-button elementor-button-link elementor-size-sm\" href=\"https:\/\/doi.org\/10.1002\/cphc.201400070\" target=\"_blank\">\n\t\t\t\t\t\t<span class=\"elementor-button-content-wrapper\">\n\t\t\t\t\t\t\t\t\t<span class=\"elementor-button-text\">Read the publication<\/span>\n\t\t\t\t\t<\/span>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-7911fab\" data-id=\"7911fab\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-c8b8a9e elementor-widget elementor-widget-image\" data-id=\"c8b8a9e\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple2.jpg\" data-elementor-open-lightbox=\"yes\" data-elementor-lightbox-title=\"RMN-exemple2\" data-e-action-hash=\"#elementor-action%3Aaction%3Dlightbox%26settings%3DeyJpZCI6MzU0MSwidXJsIjoiaHR0cHM6XC9cL3BsYXNzbWF0LmNucnMtaW1uLmZyXC93cC1jb250ZW50XC91cGxvYWRzXC8yMDIzXC8wOFwvUk1OLWV4ZW1wbGUyLmpwZyJ9\">\n\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"796\" height=\"664\" src=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple2.jpg\" class=\"attachment-full size-full wp-image-3541\" alt=\"\" srcset=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple2.jpg 796w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple2-300x250.jpg 300w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple2-768x641.jpg 768w\" sizes=\"(max-width: 796px) 100vw, 796px\" \/>\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-a5906a3 elementor-reverse-mobile elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"a5906a3\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-3ecf2d4\" data-id=\"3ecf2d4\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-fcb49bd elementor-widget elementor-widget-text-editor\" data-id=\"fcb49bd\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>The composition of the electrode\/electrolyte interface has a major influence on battery performance. NMR quantification of lithiated and fluorinated species of <sup>7<\/sup>Li and <sup>19<\/sup>F for positive LiNi<sub>0.5<\/sub>Mn<sub>0.5<\/sub> electrodes during electrochemical cycling in a LiPF<sub>6<\/sub>-type electrolyte enables direct comparison of the quantities of lithium and fluorine involved in the electrolyte degradation products at the electrode\/electrolyte interface.<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-739850f elementor-align-left elementor-mobile-align-justify elementor-widget elementor-widget-button\" data-id=\"739850f\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"button.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<div class=\"elementor-button-wrapper\">\n\t\t\t\t\t<a class=\"elementor-button elementor-button-link elementor-size-sm\" href=\"https:\/\/doi.org\/10.1016\/j.ssnmr.2011.09.001\" target=\"_blank\">\n\t\t\t\t\t\t<span class=\"elementor-button-content-wrapper\">\n\t\t\t\t\t\t\t\t\t<span class=\"elementor-button-text\">Read the publication<\/span>\n\t\t\t\t\t<\/span>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-13c086c\" data-id=\"13c086c\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-08d4b12 elementor-widget elementor-widget-image\" data-id=\"08d4b12\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple3.jpg\" data-elementor-open-lightbox=\"yes\" data-elementor-lightbox-title=\"RMN-exemple3\" data-e-action-hash=\"#elementor-action%3Aaction%3Dlightbox%26settings%3DeyJpZCI6MzU0MiwidXJsIjoiaHR0cHM6XC9cL3BsYXNzbWF0LmNucnMtaW1uLmZyXC93cC1jb250ZW50XC91cGxvYWRzXC8yMDIzXC8wOFwvUk1OLWV4ZW1wbGUzLmpwZyJ9\">\n\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"904\" height=\"624\" src=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple3.jpg\" class=\"attachment-full size-full wp-image-3542\" alt=\"\" srcset=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple3.jpg 904w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple3-300x207.jpg 300w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/08\/RMN-exemple3-768x530.jpg 768w\" sizes=\"(max-width: 904px) 100vw, 904px\" \/>\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-f47414e elementor-reverse-mobile elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"f47414e\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-38b614c\" data-id=\"38b614c\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-8690130 elementor-widget elementor-widget-text-editor\" data-id=\"8690130\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>The use of the MATPASS sequence, applied at low field (200 MHz), enables a detailed study of lithium environments within complex structures such as those of lamellar positive electrode materials like Li<sub>2<\/sub>MnO<sub>3<\/sub> (left), NMC811 (right, 1D projection) or spinels. Opposite to the MAS spectrum of NMC811 <sup>7<\/sup>Li(right, orange), the resolution using MATPASS (right, blue) ensures that there is no signal around 1300-1400 ppm, and therefore no lithium in the transition metal layers.<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-inner-column elementor-element elementor-element-2487bf0\" data-id=\"2487bf0\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-bfc1d82 elementor-widget elementor-widget-image\" data-id=\"bfc1d82\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/Fig6.jpg\" data-elementor-open-lightbox=\"yes\" data-elementor-lightbox-title=\"Fig6\" data-e-action-hash=\"#elementor-action%3Aaction%3Dlightbox%26settings%3DeyJpZCI6MzU3NywidXJsIjoiaHR0cHM6XC9cL3BsYXNzbWF0LmNucnMtaW1uLmZyXC93cC1jb250ZW50XC91cGxvYWRzXC8yMDIzXC8xMFwvRmlnNi5qcGcifQ%3D%3D\">\n\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"956\" height=\"363\" src=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/Fig6.jpg\" class=\"attachment-full size-full wp-image-3577\" alt=\"\" srcset=\"https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/Fig6.jpg 956w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/Fig6-300x114.jpg 300w, https:\/\/plassmat.cnrs-imn.fr\/wp-content\/uploads\/2023\/10\/Fig6-768x292.jpg 768w\" sizes=\"(max-width: 956px) 100vw, 956px\" \/>\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<div class=\"elementor-element elementor-element-1301eec elementor-widget-divider--view-line elementor-widget elementor-widget-divider\" data-id=\"1301eec\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"divider.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-divider\">\n\t\t\t<span class=\"elementor-divider-separator\">\n\t\t\t\t\t\t<\/span>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>Solid-state Nuclear Magnetic Resonance (NMR) provides information on the local chemical environment of the atom.<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":3805,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"elementor_header_footer","meta":{"footnotes":""},"class_list":["post-4287","page","type-page","status-publish","hentry"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.4 - 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